Synteza organiczna heterocyklicznych 1,4-benzoksazepin

Synteza organiczna heterocyklicznych 1,4-benzoksazepin

Abdellah Echchahad / BRAHIM EL GHMARI / HANANE FARAH

65,43 €
IVA incluido
Disponible
Editorial:
KS OmniScriptum Publishing
Año de edición:
2026
ISBN:
9786209570971
65,43 €
IVA incluido
Disponible

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Sobre IBD

Niniejsze badania koncentrują się na reaktywności alkoholu 2-aminobenzylowego wobec geminizowanych epoksydów (dicyjano- i cyjanoestrów), które zachowują się jako bi-elektrofile. Metoda ta umożliwia syntezę 1,4-benzoksazepin-3-onów z bardzo wysoką wydajnością poprzez proste otwarcie epoksydu, a następnie cyklizację. Wszystkie produkty zostały szczegółowo scharakteryzowane za pomocą NMR, spektrometrii mas i spektrometrii w podczerwieni z transformacją Fouriera (FT-IR). W przypadku cyjanoestrów (2) metoda umożliwia produkcję nowych 1,4-benzoksazepin w wydajnej reakcji jednopunktowej, bez potrzeby stosowania katalizatora. Prosta w wykonaniu, selektywna i osiągalna w łagodnych warunkach, metoda ta otwiera nowe perspektywy w chemii medycznej, w celu projektowania nowych związków bioaktywnych.

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