Complessi di palladio (II) contenenti un gruppo indolo

Complessi di palladio (II) contenenti un gruppo indolo

Yuichi Shimazaki

73,38 €
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Editorial:
KS OmniScriptum Publishing
Año de edición:
2026
ISBN:
9786209929472
73,38 €
IVA incluido
Disponible

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Sobre IBD

È noto che l’anello indolico del residuo triptofilico, che presenta la più elevata idrofobicità tra gli α-aminoacidi naturali, fornisce un microambiente idrofobico per il legame specifico di molecole, il trasferimento di elettroni nei sistemi biologici, i cofattori nelle metalloproteine e così via. Molti derivati dell’indolo sono noti come farmaci, quali l’indometacina, l’ergotamina, il frovatriptan, l’ondansetron e molti altri. D’altra parte, vari complessi di palladio sono noti per essere catalizzatori molto utili nelle sintesi organiche che comportano la formazione di legami C-C e l’attivazione di legami C-X. Si ritiene che la maggior parte di queste reazioni avvenga tramite intermedi Pd-C e, ad oggi, sono stati sviluppati molti complessi Pd-C, che hanno consentito di approfondire i meccanismi di reazioni catalitiche utili. Tenendo conto di questi aspetti, il presente manoscritto si concentra sulla caratterizzazione dei complessi Pd(II) contenenti un gruppo indolo, in particolare sulla formazione del legame Pd-indolo e sulle reattività dei complessi Pd-indolo.

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