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Ruthenium-NHC-katalysierte asymmetrische Arenhydrierung

Ruthenium-NHC-katalysierte asymmetrische Arenhydrierung

Christoph Schlepphorst

73,29 €
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Editorial:
Springer Nature B.V.
Año de edición:
2015
Materia
Química industrial
ISBN:
9783658089665
73,29 €
IVA incluido
Disponible

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Sobre IBD

Christoph Schlepphorst entwickelt ein rationales Ligandendesign für die Ruthenium-NHC-katalysierte asymmetrische Hydrierung (hetero-)aromatischer Verbindungen. Zudem synthetisiert er eine Reihe von entsprechenden Carbenvorläufern und charakterisiert diese. Die synthetisierten Carbenvorläufer werden außerdem auf ihre Eignung als Liganden in Ru-NHC-katalysierten Hydrierreaktionen getestet. Der Autor optimiert bei diesem Vorgehen die asymmetrische Hydrierung ungeschützter monosubstituierter Pyrazine im Hinblick auf die Reaktionsbedingungen und kann Enantiomerenverhältnisse von bis zu 91:9 mit einem der neuen Liganden erreichen.

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