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Katalytische Metathese von Alkinen

Katalytische Metathese von Alkinen

Henrike Ehrhorn

60,62 €
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Editorial:
Springer Nature B.V.
Año de edición:
2017
Materia
Química industrial
ISBN:
9783658172428
60,62 €
IVA incluido
Disponible

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Sobre IBD

Henrike Ehrhorn stellt über die „Low-Oxidation-State'-Route mehrere neue Molybdän-Alkylidin-Komplexe her. Die Autorin charakterisiert und diskutiert die Katalysatoren und Zwischenstufen NMR-spektroskopisch und mittels Röntgenstrahlbeugung am Einkristall. Außerdem untersucht sie die Aktivität der Molybdän-Komplexe in katalytischen Studien gegenüber terminalen und internen Alkinen. Hierbei weist Ehrhorn nach, dass der Triisopropylbenzylidin-Komplex eine gute Aktivität gegenüber terminalen Alkinen zeigt und der Perfluoro-tert-butanolat-haltige Molybdän-Komplex eine ungewöhnliche Reaktivität gegenüber konjugierten Diinen aufweist.

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