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Dimetallzentren in Proteinen

Dimetallzentren in Proteinen

Jennifer Marx

74,56 €
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Editorial:
Springer Nature B.V.
Año de edición:
2018
Materia
Química
ISBN:
9783658208066
74,56 €
IVA incluido
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Sobre IBD

Jennifer Marx untersucht die aktiven Zentren der R2-Proteine aus Escherichia coli, Saccharopolyspora erythraea und Geobacillus kaustophilus und diskutiert die spektroskopischen Unterschiede der Ia, Ic und der R2-artigen Gruppe der Ribonukleotidreduktasen. Sie zeigt, dass sich deren Schwingungseigenschaften bei der nuklearen inelastischen Streuung (NIS) in Abhängigkeit von den gebundenen Metallen unterscheiden. Außerdem können die für die unterschiedliche Metallbesetzung empfindlichen Bereiche der partiellen vibronischen Zustandsdichte von Eisen identifiziert werden. Um die Schwingungseigenschaften im niederfrequenten Bereich besser zu verstehen, berechnet die Autorin ein Modell des gesamten Proteins in Wasser.

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