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Badania katalityczne nowych kompleksów opartych na ligandach pirazolowych

Badania katalityczne nowych kompleksów opartych na ligandach pirazolowych

Mohamed El Boutaybi / Rachid Touzani / Zahra Bahari

93,62 €
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Editorial:
KS OmniScriptum Publishing
Año de edición:
2025
Materia
Química
ISBN:
9786208710903
93,62 €
IVA incluido
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Wydajność i selektywność metaloenzymów zawierających miedź w utlenianiu katecholu do o-chinonu przez tlen atmosferyczny skłoniła chemików koordynacyjnych do zbadania strukturalnych i katalitycznych właściwości tych enzymów. Niniejsza praca koncentruje się na syntezie nowych ligandów i kompleksów opartych na strukturach pirazolowych. Związki te zostały zbadane pod kątem ich właściwości katalitycznych w katalizowaniu reakcji utleniania katecholi i fenoli do o-chinonów oraz 2-aminofenolu do 2-aminofenoksazinonu.Celem tych badań jest znalezienie lepszych modeli dla rozwoju aktywności katalitycznej enzymów (katecholazy, tyrozynazy i syntazy fenoksazinonu), poprzez syntezę nowych kompleksów i innych kompleksów przygotowanych in situ przez pochodne pirazolu w asocjacji z metalami przejściowymi. Stwierdzono, że niektóre z tych kompleksów wykazują doskonałą aktywność katalityczną w tych reakcjach.

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